Synthesis and Properties of Higher Nuclearity Polyazanes - Université Claude Bernard Lyon 1 Access content directly
Journal Articles Chemistry - A European Journal Year : 2020

Synthesis and Properties of Higher Nuclearity Polyazanes

Abstract

Polyazanes (that is, higher nuclearity homologues of hydrazines) with increasing numbers of bound nitrogen atoms (from 3 to 5) were prepared via additions of lower order polyazanes to diazo reagents, including the first pentazane ever described. A structure was obtained. It was shown that the polynitrogen chains adopt a helical conformation. DFT modeling shows that the arrangement subsists in solution. While the polyazanes are all reducing agents, they become less so with the increasing number of nitrogens.
Fichier principal
Vignette du fichier
Angew-Thomas-2019-DEF.pdf (762.56 Ko) Télécharger le fichier
Origin : Files produced by the author(s)

Dates and versions

hal-03089670 , version 1 (28-12-2020)

Identifiers

  • HAL Id : hal-03089670 , version 1

Cite

Thomas Criton, Debora Vilona, Guy Jacob, Maurice Médebielle, Elise Dumont, et al.. Synthesis and Properties of Higher Nuclearity Polyazanes. Chemistry - A European Journal, 2020. ⟨hal-03089670⟩
206 View
215 Download

Share

Gmail Facebook X LinkedIn More