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Journal Articles Chemistry - A European Journal Year : 2020

Synthesis and Properties of Higher Nuclearity Polyazanes


Polyazanes (that is, higher nuclearity homologues of hydrazines) with increasing numbers of bound nitrogen atoms (from 3 to 5) were prepared via additions of lower order polyazanes to diazo reagents, including the first pentazane ever described. A structure was obtained. It was shown that the polynitrogen chains adopt a helical conformation. DFT modeling shows that the arrangement subsists in solution. While the polyazanes are all reducing agents, they become less so with the increasing number of nitrogens.
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hal-03089670 , version 1 (28-12-2020)


  • HAL Id : hal-03089670 , version 1


Thomas Criton, Debora Vilona, Guy Jacob, Maurice Médebielle, Elise Dumont, et al.. Synthesis and Properties of Higher Nuclearity Polyazanes. Chemistry - A European Journal, 2020. ⟨hal-03089670⟩
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