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Article Dans Une Revue Journal of Organic Chemistry Année : 2023

1,4-D-Sorbitan: A Promising Biobased-Platform for the Synthesis of Chiral Amines

Résumé

The regio- and diastereoselective synthesis of chiral amines derived from 1,4-d-sorbitan has been developed via the borrowing hydrogen reaction using a cooperative catalysis between an achiral iridium catalyst and diphenylphosphoric acid. The different reactivities of the four hydroxyl groups on the 1,4-d-sorbitan scaffold have also been highlighted.

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Chimie
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Dates et versions

hal-03967596 , version 1 (03-02-2023)

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Lucie Grand, Marian Powderly, Florence Popowycz, Maiwenn Jacolot. 1,4-D-Sorbitan: A Promising Biobased-Platform for the Synthesis of Chiral Amines. Journal of Organic Chemistry, 2023, ⟨10.1021/acs.joc.2c02827⟩. ⟨hal-03967596⟩
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