NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions - Université Claude Bernard Lyon 1 Access content directly
Journal Articles Chemical Science Year : 2022

NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions

Laura Kuehn
  • Function : Author
Ludwig Zapf
  • Function : Author
Luis Werner
  • Function : Author
Martin Stang
Sabrina Würtemberger-Pietsch
  • Function : Author
Todd Marder
Udo Radius

Abstract

Bis-NHC adducts of the type (NHC) 2 ·B 2 (OR) 4 are sources of boryl radicals of the type NHC–BR 2 ˙, which are formed by homolytic B–B bond cleavage.

Dates and versions

hal-03797498 , version 1 (04-10-2022)

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Cite

Laura Kuehn, Ludwig Zapf, Luis Werner, Martin Stang, Sabrina Würtemberger-Pietsch, et al.. NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions. Chemical Science, 2022, 13 (28), pp.8321-8333. ⟨10.1039/D2SC02096C⟩. ⟨hal-03797498⟩
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