Recyclable Ruthenium Catalyst for Distal meta ‐C−H Activation
Résumé
We disclose the unprecedented hybrid-ruthenium catalysis for distal meta-C−H activation. The hybrid-ruthenium catalyst was recyclable, as was proven by various heterogeneity tests, and fully characterized with various microscopic and spectroscopic techniques, highlighting the physical and chemical stability. Thereby, the hybrid-ruthenium catalysis proved broadly applicable for meta-C−H alkylations of among others purine-based nucleosides and natural product conjugates. Additionally, its versatility was further reflected by meta-C−H activations through visible-light irradiation, as well as para-selective C−H activations.
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Chemistry A European J - 2020 - Choi - Recyclable Ruthenium Catalyst for Distal meta%u2010C H Activation.pdf (2.64 Mo)
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